By B Monakov; Z M Sabirov; N N Sigaeva
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Extra resources for Active sites of polymerization: multiplicity: stereospecific and kinetic heterogeneity
There are different reasons for heterogeneity. For example, in the case of radical polymerization, a polymer or an initiator can be insoluble in the polymerization mixture or rather complex insoluble catalytic systems participate m ionic-coordinate polymerization processes. If polymerization shows ionic or ionic-coordinate mechanism under heterogeneous conditions, the polymeric chain is bound to transition metal atom on the catalyst surface. The chain propagates by monomer insertion (from the gas or liquid phase) between metal atoms of the active site and propagating chain [I - 5].
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